Weiyu Zhang, Yuguang Chao, Shaojun Guo. Electro-(Photo)catalysis for concurrent evolution of hydrogen and high value-added chemicals[J]. Energy Lab, 2023, 1(1): 220004. doi: 10.54227/elab.20220004
Citation: Weiyu Zhang, Yuguang Chao, Shaojun Guo. Electro-(Photo)catalysis for concurrent evolution of hydrogen and high value-added chemicals[J]. Energy Lab, 2023, 1(1): 220004. doi: 10.54227/elab.20220004

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Electro-(Photo)catalysis for concurrent evolution of hydrogen and high value-added chemicals

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  • Corresponding author: guosj@pku.edu.cn
  • Green hydrogen (H2) has been identified as a promising alternative to fossil fuel. Compared with traditional methods, such as steam methane reforming and coal gasification, electro-(photo)catalysis of water splitting provides a clean and sustainable way to produce green H2. However, electro-(photo)catalytic water splitting still suffers from sluggish kinetics and high-power consuming. Chemical-assisted electro-(photo)catalytic water splitting, with concurrent evolution of H2 and high value-added chemicals (HVACs), has recently drawn great attention. In such system, oxygen evolution process has been replaced by small organics or other chemicals with low oxidation reaction potential to reduce the energy gap. In this review, we will review recent important advances on how to design the electro-(photo)catalytic systems for concurrent evolution of H2 and HVACs. We first introduce the design principles and fundamentals of chemical-assisted electro-/photocatalytic water splitting. Then we focus on the different reaction types at anode for electro-(photo)catalysis, in which specific chemicals, especially small molecule, can be produced from biomass, alkyl alcohols and so on, with high efficiency and selectivity, coupled with promoted H2 generation. Finally, major challenges and perspectives relevant to the catalyst design, catalytic mechanisms and application of electro-(photo)catalytic concurrent evolution of H2 and HVACs will be provided.


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  • Weiyu Zhang obtained her PhD degree in Materials Physics and Chemistry from Peking University under the direction of Prof. Shaojun Guo in 2022. Her research interest focuses on the noble-metal-based nanomaterials for advanced electrocatalysis.
    Shaojun Guo is a full professor with tenure in the School of Materials Science and Engineering, Peking University, and a Fellow of the Royal Society of Chemistry. He is renowned for his leadership in nano/sub-nano/atomic materials for catalysis and energy applications. He has made outstanding contribution to the interdisciplinary fields of materials chemistry for energy electrocatalysis. He has published >200 papers in top journals as corresponding author, including 23 in Nature, Science and Nature/Science/Cell sister journals (h-index=128 and 58,000 citations). He is one of World Highly Cited Researchers from 2014 to 2021, and World Top 2 % Scientist (Stanford University).
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