Songliang Liu, Shuli Yin, Lin Cui, Hongjie Yu, Kai Deng, Ziqiang Wang, You Xu, Liang Wang, Hongjing Wang. Interface engineering-inspired electron regulation in Pt/Pd hetero-metallene for methanol-assisted hydrogen evolution[J]. Energy Lab, 2023, 1(1): 220005. doi: 10.54227/elab.20220005
Citation: Songliang Liu, Shuli Yin, Lin Cui, Hongjie Yu, Kai Deng, Ziqiang Wang, You Xu, Liang Wang, Hongjing Wang. Interface engineering-inspired electron regulation in Pt/Pd hetero-metallene for methanol-assisted hydrogen evolution[J]. Energy Lab, 2023, 1(1): 220005. doi: 10.54227/elab.20220005

RESEARCH ARTICLE

Interface engineering-inspired electron regulation in Pt/Pd hetero-metallene for methanol-assisted hydrogen evolution

More Information
  • Corresponding author: hjw@zjut.edu.cn
  • The small molecule oxidation reaction instead of oxygen evolution reaction coupled with hydrogen evolution reaction can greatly reduce the reaction overpotential of electrochemical water splitting, which is a very efficient and energy-saving hydrogen evolution strategy. Herein, we report an interface engineering constructed two-dimensional ultrathin curled Pt/Pd hetero-metallene for efficient electrocatalytic hydrogen evolution assisted by methanol. The thin-sheet structure of Pt/Pd hetero-metallene provides a large specific surface area and exposes numerous surface atoms that could act as reactive sites, thus accelerating the reaction mass transfer process. More importantly, the constructed Pt/Pd hetero-metallene possesses abundant Pt/Pd heterointerface, which can maximize the strong metal-metal interaction and increase the utilization of metal atoms, thereby optimizing the adsorption and activation of reactants during the reaction. Pt/Pd hetero-metallene can produce hydrogen stably and efficiently in 1 M KOH + 1 M CH3OH, and the voltage only needs 0.83 V at @100 mA cm−2 when used in electrocatalytic hydrogen evolution, which is much lower than the voltage required for the traditional electrochemical water splitting process (1.94 V). This work not only provides a powerful approach to rational design and construction of hetero-metallene through interface engineering, but also builds a bridge between hetero-metallene and methanol-assisted hydrogen evolution.


  • 加载中
  • 1. Z. Zhao, H. Liu, W. Gao, W. Xue, Z. Liu, J. Huang, X. Pan, Y. Huang, J. Am. Chem. Soc., 2018, 140, 9046
    2. Y. Li, C. K. Peng, H. Hu, S. Y. Chen, J. H. Choi, Y. G. Lin, J. Lee, M, Nat. Commun., 2022, 13, 1143
    3. Z. L. Wang, K. Sun, J. Henzie, X. Hao, C. Li, T. Takei, Y. M. Kang, Y. Yamauchi, Angew. Chem. Int. Ed., 2018, 57, 5848
    4. K. Wang, B. Huang, F. Lin, F. Lv, M. Luo, P. Zhou, Q. Liu, W. Zhang, C. Yang, Y. Tang, Y. Yang, W. Wang, H. Wang, S. Guo, Adv. Energy Mater., 2018, 8, 1801891
    5. Y. Guo, J. Tang, Z. Wang, Y.-M. Kang, Y. Bando, Y. Yamauchi, Nano Energy, 2018, 47, 494
    6. X. Wu, J. Li, Y. Li, Z. Wen, Chem. Eng. J., 2021, 409, 128161
    7. M. Zhang, J. Chen, H. Li, P. Cai, Y. Li, Z. Wen, Nano Energy, 2019, 61, 576
    8. Y. Xu, X. Chai, T. Ren, S. Yu, H. Yu, Z. Wang, X. Li, L. Wang, H. Wang, Chem. Commun., 2020, 56, 2151
    9. S. Fang, X. Zhu, X. Liu, J. Gu, W. Liu, D. Wang, W. Zhang, Y. Lin, J. Lu, S. Wei, Y. Li, T. Yao, Nat. Commun., 2020, 11, 1029
    10. A. Ali, P. K. Shen, Carbon Energy, 2019, 2, 99
    11. Q. Mao, K. Deng, W. Wang, P. Wang, Y. Xu, Z. Wang, X. Li, L. Wang, H. Wang, J. Mater. Chem. A, 2022, 10, 8364
    12. W. Zhang, B. Huang, K. Wang, W. Yang, F. Lv, N. Li, Y. Chao, P. Zhou, Y. Yang, Y. Li, J. Zhou, W. Zhang, Y. Du, D. Su, S. Guo, Adv. Energy Mater., 2020, 11, 2003192
    13. J. Xu, I. Amorim, Y. Li, J. Li, Z. Yu, B. Zhang, A. Araujo, N. Zhang, L. Liu, Carbon Energy, 2020, 2, 646
    14. H. Huang, Y. Zhao, Y. Bai, F. Li, Y. Zhang, Y. Chen, Adv. Sci., 2020, 7, 2000012
    15. G. Zhou, M. Li, Y. Li, H. Dong, D. Sun, X. Liu, L. Xu, Z. Tian, Y. Tang, Adv. Funct. Mater., 2019, 30, 1905252
    16. W. Song, M. Li, C. Wang, X. Lu, Carbon Energy, 2020, 3, 101
    17. K. Kani, H. Lim, A. E. Whitten, K. Wood, A. J. E. Yago, M. S. A. Hossain, J. Henzie, J. Na, Y. Yamauchi, J. Mater. Chem. A, 2021, 9, 2754
    18. W. Zhou, T. Jia, D. Zhang, Z. Zheng, W. Hong, X. Chen, Appl. Catal. B: Environ., 2019, 259, 118067
    19. L. Chen, J. Shi, J. Mater. Chem. A, 2018, 6, 13538
    20. K. Deng, Q. Mao, W. Wang, P. Wang, Z. Wang, Y. Xu, X. Li, H. Wang, L. Wang, Appl. Catal. B: Environ., 2022, 310, 121338
    21. Y. Xu, M. Liu, S. Wang, K. Ren, M. Wang, Z. Wang, X. Li, L. Wang, H. Wang, Appl. Catal. B: Environ., 2021, 298, 120493
    22. J. Y. Zhang, H. Wang, Y. Tian, Y. Yan, Q. Xue, T. He, H. Liu, C. Wang, Y. Chen, B. Y. Xia, Angew. Chem. Int. Ed., 2018, 57, 7649
    23. C. Lin, P. Zhang, S. Wang, Q. Zhou, B. Na, H. Li, J. Tian, Y. Zhang, C. Deng, L. Meng, J. Wu, C. Liu, J. Hu, L. Zhang, Journal of Alloys and Compounds, 2020, 823, 153784
    24. K. Xiang, D. Wu, X. Deng, M. Li, S. Chen, P. Hao, X. Guo, J. L. Luo, X. Z. Fu, Adv. Funct. Mater., 2020, 30, 1909610
    25. G. Ma, X. Zhang, G. Zhou, X. Wang, Chem. Eng. J., 2021, 411, 128292
    26. S. Yin, S. Liu, Z. Wang, Y. Xu, X. Li, H. Wang, L. Wang, Chem. Eng. J., 2022, 435, 134711
    27. Y. Shi, Z. R. Ma, Y. Y. Xiao, Y. C. Yin, W. M. Huang, Z. C. Huang, Y. Z. Zheng, F. Y. Mu, R. Huang, G. Y. Shi, Y. Y. Sun, X. H. Xia, W. Chen, Nat. Commun., 2021, 12, 3021
    28. J. Chen, M. Qin, S. Ma, R. Fan, X. Zheng, S. Mao, C. Chen, Y. Wang, Appl. Catal. B: Environ., 2021, 299, 120640
    29. H.-S. Chen, T. M. Benedetti, J. Lian, S. Cheong, P. B. O’Mara, K. O. Sulaiman, C. H. W. Kelly, R. W. J. Scott, J. J. Gooding, R. D. Tilley, ACS Catal., 2021, 11, 2235
    30. Z. Zhang, J. Liu, J. Wang, Q. Wang, Y. Wang, K. Wang, Z. Wang, M. Gu, Z. Tang, J. Lim, T. Zhao, F. Ciucci, Nat. Commun., 2021, 12, 5235
    31. Q. Yang, H. Liu, P. Yuan, Y. Jia, L. Zhuang, H. Zhang, X. Yan, G. Liu, Y. Zhao, J. Liu, S. Wei, L. Song, Q. Wu, B. Ge, L. Zhang, K. Wang, X. Wang, C. R. Chang, X. Yao, J. Am. Chem. Soc., 2022, 144, 2171
    32. H. Wang, S. Yin, Y. Xu, X. Li, A. A. Alshehri, Y. Yamauchi, H. Xue, Y. V. Kaneti, L. Wang, J. Mater. Chem. A, 2018, 6, 8662
    33. T. J. Wang, Y. C. Jiang, J. W. He, F. M. Li, Y. Ding, P. Chen, Y. Chen, Carbon Energy, 2022, 4, 283
    34. X. Zhao, X. Li, D. Xiao, M. Gong, L. An, P. Gao, J. Yang, D. Wang, Appl. Catal. B: Environ, 2021, 295, 120280
    35. J. Fan, J. Wu, X. Cui, L. Gu, Q. Zhang, F. Meng, B. H. Lei, D. J. Singh, W. Zheng, J. Am. Chem. Soc., 2020, 142, 3645
    36. K. Zhu, J. Ma, L. Chen, F. Wu, X. Xu, M. Xu, W. Ye, Y. Wang, P. Gao, Y. Xiong, ACS Catal., 2022, 12, 4840
    37. J. Liang, S. Li, Y. Chen, X. Liu, T. Wang, J. Han, S. Jiao, R. Cao, Q. Li, J. Mater. Chem. A, 2020, 8, 15665
    38. J. Zhang, F. Lv, Z. Li, G. Jiang, M. Tan, M. Yuan, Q. Zhang, Y. Cao, H. Zheng, L. Zhang, C. Tang, W. Fu, C. Liu, K. Liu, L. Gu, J. Jiang, G. Zhang, S. Guo, Adv. Mater., 2022, 34, e2105276
    39. X. Mu, J. Gu, F. Feng, Z. Xiao, C. Chen, S. Liu, S. Mu, Adv. Sci., 2021, 8, 2002341
    40. Q. Mao, P. Wang, Z. Wang, Y. Xu, X. Li, L. Wang, H. Wang, Appl. Mater. Today, 2022, 26, 101400
    41. C. Cao, Q. Xu, Q.-L. Zhu, Chem Catal., 2022, 2, 693
    42. C. Tang, S.-Z. Qiao, Matter, 2019, 1, 1454
    43. F. Lv, B. Huang, J. Feng, W. Zhang, K. Wang, N. Li, J. Zhou, P. Zhou, W. Yang, Y. Du, D. Su, S. Guo, Natl. Sci. Rev., 2021, 8, nwab019
    44. M. Luo, Z. Zhao, Y. Zhang, Y. Sun, Y. Xing, F. Lv, Y. Yang, X. Zhang, S. wang, Y. Qin, J. Y. Ma, F. Lin, D. Su, G. Lu, S. Guo, Nature, 2019, 574, 81
    45. Q. Yun, Q. Lu, C. Li, B. Chen, Q. Zhang, Q. He, Z. Hu, Z. Zhang, Y. Ge, N. Yang, J. Ge, Y. B. He, L. Gu, H. Zhang, ACS Nano, 2019, 13, 14329
    46. L. Y. Zhang, F. Wang, S. Wang, H. Huang, X. Meng, Y. Ouyang, W. Yuan, C. X. Guo, C. M. Li, Adv. Funct. Mater., 2020, 30, 2003933
    47. L. Shi, Q. Wang, Q. Ren, Q. Yang, D. Zhao, Y. Feng, H. Chen, Y. Wang, Small, 2022, 18, e2103665
    48. B. Zhang, G. Zhao, B. Zhang, L. Xia, Y. Jiang, T. Ma, M. Gao, W. Sun, H. Pan, Adv. Mater., 2021, 33, e2105400
    49. Y. Yan, H. Shan, G. Li, F. Xiao, Y. Jiang, Y. Yan, C. Jin, H. Zhang, J. Wu, D. Yang, Nano Lett., 2016, 16, 7999
    50. Z. Zhang, Y. Liu, B. Chen, Y. Gong, L. Gu, Z. Fan, N. Yang, Z. Lai, Y. Chen, J. Wang, Y. Huang, M. Sindoro, W. Niu, B. Li, Y. Zong, Y. Yang, X. Huang, F. Huo, W. Huang, H. Zhang, Adv. Mater., 2016, 28, 10282
    51. H. Yu, T. Zhou, Z. Wang, Y. Xu, X. Li, L. Wang, H. Wang, Angew. Chem. Int. Ed, 2021, 60, 12027
    52. R. Wu, Y. Li, W. Gong, P. K. Shen, ACS Sustainable Chem. Eng., 2019, 7, 8419
    53. H. Wang, S. Jiao, S. Liu, S. Wang, T. Zhou, Y. Xu, X. Li, Z. Wang, L. Wang, ACS Appl. Mater. Interfaces, 2021, 13, 30479
    54. M. Farsadrooh, J. Torrero, L. Pascual, M. A. Peña, M. Retuerto, S. Rojas, Appl. Catal. B: Environ., 2018, 237, 866
    55. K. Deng, T. Zhou, Q. Mao, S. Wang, Z. Wang, Y. Xu, X. Li, H. Wang, L. Wang, Adv. Mater., 2022, 34, e2110680
    56. B. Jiang, Y. Guo, J. Kim, A. E. Whitten, K. Wood, K. Kani, A. E. Rowan, J. Henzie, Y. Yamauchi, J. Am. Chem. Soc., 2018, 140, 12434
    57. C. Tang, N. Zhang, Y. Ji, Q. Shao, Y. Li, X. Xiao, X. Huang, Nano Lett., 2019, 19, 1336
    58. L. Zhai, X. She, L. Zhuang, Y. Li, R. Ding, X. Guo, Y. Zhang, Y. Zhu, K. Xu, H. J. Fan, S. P. Lau, Angew. Chem. Int. Ed., 2022, 61, e202116057
    59. Z. Li, Y. Pei, R. Ma, Y. Wang, Y. Zhu, M. Yang, J. Wang, J. Mater. Chem. A, 2021, 9, 13109
  • This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

  • Supporting_Information-2022-0005.R1
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(7)

Information

Article Metrics

Article views(3168) PDF downloads(888) Citation(0)

Article Contents

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint