| Citation: |
Lai Yu, Jie Li, Nazir Ahmad, Xiaoyue He, Rong Liu, Xinyi Ma, Jianming Li, Anqiang Pan, Genqiang Zhang. Synergistic manipulation of micro-phosphorus and sulphur incorporation on carbonaceous cathode endows superior zinc-ion storage performance[J]. Energy Lab, 2024, 2(2): 240002. doi: 10.54227/elab.20240002
|
Synergistic manipulation of micro-phosphorus and sulphur incorporation on carbonaceous cathode endows superior zinc-ion storage performance
-
Abstract
Aqueous zinc-ion hybrid capacitors (ZHCs) stand out as emerging electrochemical energy storage systems, combining the merits of low cost and impressive theoretical capacity. Nevertheless, unsatisfactory energy density and cycle life of ZHCs limit their widespread application. Herein, a simple one-pot approach was introduced to mitigate the issues through phosphorus and sulfur synergistically activated carbon nanosheets with hierarchically porous architecture (PS-HPCNS), deemed as a potential cathode candidate. The PS-HPCNS can show an excellent Zn-ion storage performance, including a high electrochemical capacity of 240.1 mAh g−1 under 0.2 A g−1, a decent energy density of 139.3 Wh kg−1 at 116 W kg−1, also a long cycle life over
50000 cycles with 84.6% capacity retention. Theoretical simulations combined with experimental analysis indicate that P and S dual-doping can enhance pseudocapacitance, significantly boost the interaction with Zn2+ ions and improve reaction kinetics. This work offers an appealing route to construct carbon cathode with superior zinc-ion storage ability and gives significant guidance towards advancing energy storage technologies. -
-
References
1. S. Alvin, H. S. Cahyadi, J. Hwang, W. Chang, S. K. Kwak, J. Kim, Adv. Energy Mater., 2020, 10, 2000283 2. C. Zhang, M. Liang, S.-H. Park, Z. Lin, A. Seral-Ascaso, L. Wang, A. Pakdel, C. Ó. Coileáin, J. Boland, O. Ronan, N. McEvoy, B. Lu, Y. Wang, Y. Xia, J. N. Coleman, V. Nicolosi, Energy Environ. Sci., 2020, 13, 2124 3. B. Yong, D. Ma, Y. Wang, H. Mi, C. He, P. Zhang, Adv. Energy Mater., 2020, 10, 2002354 4. H. Li, L. Ma, C. Han, Z. Wang, Z. Liu, Z. Tang, C. Zhi, Nano Energy, 2019, 62, 550 5. Y. F. Xu, Y. C. Du, H. Chen, J. Chen, T. J. Ding, D. M. Sun, D. H. Kim, Z. Q. Lin, X. S. Zhou, Chem. Soc. Rev., 2024, 53, 7202 6. Y. H. Man, P. Jaumaux, Y. F. Xu, Y. T. Fei, X. Y. Mo, G. X. Wang, X. S. Zhou, Sci. Bull., 2023, 68, 1819-1842 7. H. Tang, J. Yao, Y. Zhu, Adv. Energy Mater., 2021, 11, 2003994 8. L. Wu, Y. Dong, Energy Storage Mater., 2021, 41, 715 9. S. Tang, C. Wang, X. Pu, X. Gu, Z. Chen, Acta Phys.-Chim. Sin., 2023, 39, 2212037 10. S. Gheytani, Y. Liang, F. Wu, Y. Jing, H. Dong, K. K. Rao, X. Chi, F. Fang, Y. Yao, Adv. Sci., 2017, 4, 1700465 11. Z. Wang, M. Zhang, W. Ma, J. Zhu, W. Song, Small, 2021, 17, 2100219 12. J. Yin, W. Zhang, N. A. Alhebshi, N. Salah, H. N. Alshareef, Adv. Energy Mater., 2021, 11, 2100201 13. Q. Liu, H. Zhang, J. Xie, X. Liu, X. Lu, Carbon Energy, 2020, 2, 521 14. Z. Li, Y. An, S. Dong, C. Chen, L. Wu, Y. Sun, X. Zhang, Energy Storage Mater., 2020, 31, 252 15. L. Dong, X. Ma, Y. Li, L. Zhao, W. Liu, J. Cheng, C. Xu, B. Li, Q.-H. Yang, F. Kang, Energy Storage Mater., 2018, 13, 96 16. Z. Huang, A. Chen, F. Mo, G. Liang, X. Li, Q. Yang, Y. Guo, Z. Chen, Q. Li, B. Dong, C. Zhi, Adv. Energy Mater., 2020, 10, 2001024 17. G. Yang, J. Huang, X. Wan, Y. Zhu, B. Liu, J. Wang, P. Hiralal, O. Fontaine, Y. Guo, H. Zhou, Nano Energy, 2021, 90, 106500 18. C.-C. Hou, Y. Wang, L. Zou, M. Wang, H. Liu, Z. Liu, H. F. Wang, C. Li, Q. Xu, Adv. Mater., 2021, 33, 2101698 19. R. Fei, H. Wang, Q. Wang, R. Qiu, S. Tang, R. Wang, B. He, Y. Gong, H. J. Fan, Adv. Energy Mater, 2020, 10, 2002741 20. H. Zhang, Z. Chen, Y. Zhang, Z. Ma, Y. Zhang, L. Bai, L. Sun, J. Mater. Chem. A, 2021, 9, 16565 21. L. Huang, Y. Xiang, M. Luo, Q. Zhang, H. Zhu, K. Shi, S. Zhu, Carbon, 2021, 185, 1 22. Q. Sun, D. Li, J. Cheng, L. Dai, J. Guo, Z. Liang, L. Ci, Carbon, 2019, 155, 601 23. Y. Qian, Y. Li, Z. Yi, J. Zhou, Z. Pan, J. Tian, Y. Wang, S. Sun, N. Lin, Y. Qian, Adv. Funct. Mater., 2020, 31, 2006875 24. X. Zheng, J. Wu, X. Cao, J. Abbott, C. Jin, H. Wang, P. Strasser, R. Yang, X. Chen, G. Wu, Applied Catalysis B: Environmental, 2019, 241, 442 25. X. Hu, G. Zhong, J. Li, Y. Liu, J. Yuan, J. Chen, H. Zhan, Z. Wen, Energy Environ. Sci., 2020, 13, 2431 26. W. Li, M. Zhou, H. Li, K. Wang, S. Cheng, K. Jiang, Energy Environ. Sci., 2015, 8, 2916 27. Y. Liu, Y. Ouyang, D. Huang, C. Jiang, X. Liu, Y. Wang, Y. Dai, D. Yuan, J. W. Chew, Sci. Total Environ., 2020, 706, 136019 28. K. Kubota, S. Shimadzu, N. Yabuuchi, S. Tominaka, S. Shiraishi, M. Abreu-Sepulveda, A. Manivannan, K. Gotoh, M. Fukunishi, M. Dahbi, S. Komaba, Chem. Mater., 2020, 32, 2961 29. D. Han, S. Wu, S. Zhang, Y. Deng, C. Cui, L. Zhang, Y. Long, H. Li, Y. Tao, Z. Weng, Q. H. Yang, F. Kang, Small, 2020, 16, 2001736 30. X. Shi, H. Zhang, S. Zeng, J. Wang, X. Cao, X. Liu, X. Lu, ACS Materials Lett., 2021, 3, 1291 31. Y. Lu, Z. Li, Z. Bai, H. Mi, C. Ji, H. Pang, C. Yu, J. Qiu, Nano Energy, 2019, 66, 104132 32. Z. Wang, J. Huang, Z. Guo, X. Dong, Y. Liu, Y. Wang, Y. Xia, Joule, 2019, 3, 1289 33. D. Wu, C. Ji, H. Mi, F. Guo, H. Cui, P. Qiu, N. Yang, Nanoscale, 2021, 13, 15869 34. H. He, J. Lian, C. Chen, Q. Xiong, M. Zhang, Chem. Eng. J., 2021, 421, 129786 35. H. Fan, X. Hu, S. Zhang, Z. Xu, G. Gao, Y. Zheng, G. Hu, Q. Chen, T. S. AlGarni, R. Luque, Carbon, 2021, 180, 254 36. J. Yin, W. Zhang, W. Wang, N. A. Alhebshi, N. Salah, H. N. Alshareef, Adv. Energy Mater., 2020, 10, 2001705 37. Y. Shao, Z. Sun, Z. Tian, S. Li, G. Wu, M. Wang, X. Tong, F. Shen, Z. Xia, V. Tung, J. Sun, Y. Shao, Adv. Funct. Mater, 2020, 31, 2007843 38. H. Xu, W. He, Z. Li, J. Chi, J. Jiang, K. Huang, S. Li, G. Sun, H. Dou, X. Zhang, Adv. Funct. Mater, 2022, 2111131 39. Y. Li, W. Yang, W. Yang, Z. Wang, J. Rong, G. Wang, C. Xu, F. Kang, L. Dong, Nano-Micro Lett., 2021, 13, 95 40. Y. Yang, D. Chen, H. Wang, P. Ye, Z. Ping, J. Ning, Y. Zhong, Y. Hu, Chem. Eng. J., 2022, 431, 133250 41. L. Wang, M. Peng, J. Chen, X. Tang, L. Li, T. Hu, K. Yuan, Y. Chen, ACS Nano, 2022, 16, 2877 42. P. Liu, W. Liu, Y. Huang, P. Li, J. Yan, K. Liu, Energy Storage Mater., 2020, 25, 858 43. Z. Tie, L. Liu, S. Deng, D. Zhao, Z. Niu, Angew. Chem. Int. Ed., 2020, 59, 4920 44. X. Deng, J. Li, Z. Shan, J. Sha, L. Ma, N. Zhao, J. Mater. Chem., 2020, 8, 11617 45. H. Zhang, Q. Liu, Y. Fang, C. Teng, X. Liu, P. Fang, Y. Tong, X. Lu, Adv. Mater., 2019, 31, 1904948 46. C. Lv, W. Xu, H. Liu, L. Zhang, S. Chen, X. Yang, X. Xu, D. Yang, Small, 2019, 15, 1900816 47. Q. Jin, W. Li, K. Wang, H. Li, P. Feng, Z. Zhang, W. Wang, K. Jiang, Adv. Funct. Mater., 2020, 30, 1909907 -
Rights and permissions
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
-
Supplementary Information
ENLAB-2024-0002-suppl 
Figures(7)
Information
Article Metrics
Export File
Citation
Lai Yu, Jie Li, Nazir Ahmad, Xiaoyue He, Rong Liu, Xinyi Ma, Jianming Li, Anqiang Pan, Genqiang Zhang. Synergistic manipulation of micro-phosphorus and sulphur incorporation on carbonaceous cathode endows superior zinc-ion storage performance[J]. Energy Lab, 2024, 2(2): 240002. doi: 10.54227/elab.20240002
Format
Content
DownLoad:
-
Figure 1.
a Schematic illustration of the preparation process of PS-HPCNS. b SEM image of C-TDP/PA-K. c SEM, d TEM and e HRTEM images of PS-HPCNS. f Corresponding elemental mappings (C, S, and P) of PS-HPCNS. g N2 adsorption-desorption isotherms, complemented by the pore size distribution analysis of PS-HPCNS.
-
Figure 2.
a Typical XRD patterns and b XPS survey spectra of PS-HPCNS and S-PC; High-resolution c C 1s, d S 2p and e P 2p XPS spectra of PS-HPCNS; f Raman spectra of PS-HPCNS and S-PC.
-
Figure 3.
a the ZHC based on the PS-HPCNS cathode; b rate capability of the PS-HPCNS and S-PC based ZHCs; c Galvanostatic charge-discharge profiles of PS-HPCNS cathode; d Ragone plots, and e ultralong cycling performance of the assembled ZHC with the PS-HPCNS cathode at 10 A g−1.
-
Figure 4.
a-b CV profiles of PS-HPCNS and S-PC cathode; c The fitting plot between log(i) and log(v); d The capacitive contributions at 10 mV s−1; e Normalized capacitive contributions at different scan rates; (f) Nyquist plots of PS-HPCNS and S-PC cathodes.
-
Figure 5.
Energy storage mechanism of the ZHC based on the PS-HPCNS cathode. a The discharge and charge profiles at 0.2 A g−1; The ex-situ XRD patterns of b Zn|In anode and c PS-HPCNS cathode; d Ex situ SEM images of PS-HPCNS cathode; e In situ Raman spectroscopy and f ex-situ XPS spectra of C 1s.
-
Figure 6.
Theoretical calculations for zinc storage behavior. Top and side illustration of simulations for Zn ions adsorbed in the a pristine carbon, b S-PC and c PS-HPCNS models. The different charge densities of Zn ions adsorbed in the d pristine carbon, e S-PC, and f PS-HPCNS. Corresponding DOS illustrations of different carbon structures g before and h after Zn ion adsorption. The cyan and yellow regions display charge depletion and accumulation, respectively. The brown, red, yellow, and blue colors indicate C, O, S, and P atoms, respectively.
